Array ( [0] => 16587648 [id] => 16587648 [1] => cswiki [site] => cswiki [2] => Tricyklodekan [uri] => Tricyklodekan [3] => [img] => [4] => [day_avg] => [5] => [day_diff] => [6] => [day_last] => [7] => [day_prev_last] => [8] => [oai] => [9] => [is_good] => [10] => [object_type] => [11] => 0 [has_content] => 0 [12] => [oai_cs_optimisticky] => ) Array ( [0] => {{Infobox - chemická sloučenina [1] => | název = Tricyklodekan [2] => | obrázek = Tricyclodecane-endo-flat.svg [3] => | velikost obrázku = 175px [4] => | popisek = Strukturní vzorec ''endo''-tricyklodekanu [5] => | obrázek2 = Tricyclodecane-exo-flat.svg [6] => | velikost obrázku2 = 175px [7] => | popisek2 = Strukturní vzorec ''exo''-tricyklodekanu [8] => | systematický název = tricyklo[5.2.1.02,6]dekan [9] => | ostatní názvy = tetrahydrodicyklopentadien [10] => | sumární vzorec = C10H16 [11] => | číslo CAS = 6004-38-2 [12] => | číslo EINECS = 227-851-2 [13] => | PubChem = 17795 [14] => | SMILES = C1CC2C3CCC(C3)C2C1 [15] => | InChI = 1S/C10H16/c1-2-9-7-4-5-8(6-7)10(9)3-1/h7-10H,1-6H2 [16] => | molární hmotnost = 136,23 g/mol [17] => | symboly nebezpečí GHS = {{GHS02}} {{GHS07}} {{GHS08}} {{GHS09}}https://pubchem.ncbi.nlm.nih.gov/compound/17795 [18] => | H-věty = {{H|226}} {{H|304}} {{H|315}} {{H|317}} {{H|319}} {{H|400}} {{H|410}} [19] => | P-věty = {{P|210}} {{P|233}} {{P|240}} {{P|241}} {{P|242}} {{P|243}} {{P|261}} {{P|264+265}} {{P|270}} {{P|272}} {{P|273}} {{P|280}} {{P|301+316}} {{P|302+352}} {{P|303+361+353}} {{P|305+351+338}} {{P|321}} {{P|331}} {{P|332+317}} {{P|333+317}} {{P|337+317}} {{P|362+364}} {{P|370+378}} {{P|391}} {{P|403+235}} {{P|405}} {{P|501}} [20] => }} [21] => '''Tricyklodekan''' (zkráceně '''TCD''') je [[tricyklická molekula|tricyklický]] [[uhlovodíky|uhlovodík]] se vzorcem C10H16. Vytváří dva [[stereoizomerie|stereoizomery]], [[endo-exo izomerie|''endo'' a ''exo'']].{{Citace elektronické monografie | titul = Exo-tricyclo[5.2.1.0(2.6)]decane | url = https://webbook.nist.gov/cgi/cbook.cgi?ID=U215287&Units=SI&Mask=80 | datum přístupu = 2023-10-03}} [22] => [23] => ''Exo'' forma má využití jako složka paliv pro [[reaktivní motor|tryskové motory]],{{Citace periodika | autor1 = Jason M. Hudzik | autor2 = Rubik Asatryan | autor3 = Joseph W. Bozzelli | titul = Thermochemical Properties of exo -Tricyclo[5.2.1.0 2,6 ]decane (JP-10 Jet Fuel) and Derived Tricyclodecyl Radicals | periodikum = [[The Journal of Physical Chemistry A]] | datum vydání = 2010-09-09 | strany = 9545–9553 | url = https://pubs.acs.org/doi/10.1021/jp1049556 | issn = 1089-5639 | doi = 10.1021/jp1049556 | pmid = 20712369 | bibcode = 2010JPCA..114.9545H}} kde je vhodná díky své vysoké [[hustota energie|hustotě energie]]. ''Exo''-izomer se také vyznačuje nízkou [[teplota tání|teplotou tání]].{{Citace periodika | autor1 = Olivier Herbinet | autor2 = Baptiste Sirjean | autor3 = Roda Bounaceur | autor4 = René Fournet | autor5 = Frédérique Battin-Leclerc | autor6 = Gérard Scacchi | autor7 = Paul-Marie Marquaire | titul = Primary Mechanism of the Thermal Decomposition of Tricyclodecane | periodikum = The Journal of Physical Chemistry A | datum vydání = 2006-10-01 | strany = 11298–11314 | url = https://pubs.acs.org/doi/10.1021/jp0623802 | issn = 1089-5639 | doi = 10.1021/jp0623802 | pmid = 17004739 | bibcode = 2006JPCA..11011298H}}{{Citace periodika | autor1 = Junjun Wu | autor2 = Lu Gem Gao | autor3 = Hongbo Ning | autor4 = Wei Ren | autor5 = Donald G. Truhlar | titul = Direct dynamics of a large complex hydrocarbon reaction system: The reaction of OH with exo-tricyclodecane (the main component of Jet Propellant-10) | periodikum = Combustion and Flame | rok vydání = 2020 | strany = 82–91 | url = https://www.sciencedirect.com/science/article/pii/S0010218020300821 | issn = 0010-2180 | doi = 10.1016/j.combustflame.2020.02.019}} [24] => [25] => Z důvodu těchto vlastností byly vlastnosti tricyklodekanu podrobně zkoumány.{{Citace elektronické monografie | titul = Exo-tricyclo[5.2.1.0(2.6)]decane | url = https://www.chemeo.com/cid/70-324-4/Exo-tricyclo-5-2-1-0-2-6-decane | datum přístupu = 2023-10-03}}{{Citace periodika | autor1 = R. Seiser | autor2 = U. Niemann | autor3 = K. Seshadri | titul = Experimental study of combustion of n-decane and JP-10 in non-premixed flows | periodikum = Proceedings of the Combustion Institute | rok vydání = 2011 | strany = 1045–1052 | url = https://www.sciencedirect.com/science/article/pii/S1540748910001380 | issn = 1540-7489 | doi = 10.1016/j.proci.2010.06.078}}{{Citace periodika | autor1 = Yujie Tao | spoluautoři = Rui Xu, Kun Wang, Jiankun Shao, Sarah E. Johnson, Ashkan Movaghar, Xu Han, Ji-Woong Park, Tianfeng Lu, Kenneth Brezinsky, Fokion N. Egolfopoulos, David F. Davidson, Ronald K. Hanson, Craig T. Bowman, Hai Wang | titul = A Physics based approach to modeling real fuel combustion chemistry III Reaction kinetic model of JP10 | periodikum = Combustion and Flame | rok vydání = 2018 | strany = 466–476 | url = https://www.sciencedirect.com/science/article/pii/S0010218018303870 | issn = 0010-2180 | doi = 10.1016/j.combustflame.2018.08.022}}{{Citace periodika | autor1 = Heng Li | autor2 = Guozhu Liu | autor3 = Rongpei Jiang | autor4 = Li Wang | autor5 = Xiangwen Zhang | titul = Experimental and kinetic modeling study of exo-TCD pyrolysis under low pressure | periodikum = Combustion and Flame | rok vydání = 2015 | strany = 2177–2190 | url = https://www.sciencedirect.com/science/article/pii/S0010218015000188 | issn = 0010-2180 | doi = 10.1016/j.combustflame.2015.01.015}}{{Citace periodika | autor1 = K. H. H. Goh | autor2 = P. Geipel | autor3 = F. Hampp | autor4 = R. P. Lindstedt | titul = Regime transition from premixed to flameless oxidation in turbulent JP-10 flames | periodikum = Proceedings of the Combustion Institute | rok vydání = 2013 | strany = 3311–3318 | url = https://www.sciencedirect.com/science/article/pii/S1540748912002817 | issn = 1540-7489 | doi = 10.1016/j.proci.2012.06.173}} [26] => [27] => == Reaakce == [28] => Reakce tricyklodekanu byly zkoumány za využití několika různých způsobů přípravy výchozí látky.{{Citace elektronické monografie | titul = STTR Navy FY09A - Characterization of the High Temperature Decomposition Products of JP-10 | url = https://www.navysbir.com/n09_s/navst09-011.htm | datum přístupu = 2023-10-03}}{{Citace periodika | autor1 = Junjun Wu | autor2 = Lu Gem Gao | autor3 = Hongbo Ning | autor4 = Wei Ren | autor5 = Donald G. Truhlar | titul = Direct dynamics of a large complex hydrocarbon reaction system: The reaction of OH with exo-tricyclodecane (the main component of Jet Propellant-10) | periodikum = Combustion and Flame | rok vydání = 2020 | strany = 82–91 | url = https://www.sciencedirect.com/science/article/pii/S0010218020300821 | issn = 0010-2180 | doi = 10.1016/j.combustflame.2020.02.019}}{{Citace elektronického periodika [29] => | titul = US2766301A Production of tricyclodecane [30] => | periodikum = worldwide.espacenet.com [31] => | url = https://worldwide.espacenet.com/patent/search/family/023684943/publication/US2766301A?q=pn=US2766301 [32] => | datum přístupu = 2024-01-12 [33] => }}{{Citace elektronické monografie | autor = Sirjean Baptiste | titul = Theoretical Study of the Thermal Decomposition of a Jet Fuel Surrogate | url = https://hal.science/hal-00377675/document}} [34] => [35] => Jednotlivé izomery se za přítomnosti [[chlorid hlinitý|chloridu hlinitého]], absorbovaného na [[oxid křemičitý|oxidu křemičitém]] nebo [[zeolit]]ech, mohou přeměňovat jeden v druhý,{{Citace periodika | autor1 = Cong-ming Sun | autor2 = Gang Li | titul = Vapor-phase isomerization of endo-tetrahydrodicyclopentadiene to its exo isomer over zeolite catalysts | periodikum = [[Applied Catalysis A: General]] | rok vydání = 2011 | strany = 196–200 | url = https://www.sciencedirect.com/science/article/pii/S0926860X11003437 | issn = 0926-860X | doi = 10.1016/j.apcata.2011.06.008}}{{Citace periodika | autor1 = Pablo del Campo | autor2 = Cristina Martínez | autor3 = Avelino Corma | titul = Activation and conversion of alkanes in the confined space of zeolite-type materials | periodikum = [[Chemical Society Reviews]] | datum vydání = 2021-08-02 | strany = 8511–8595 | url = https://pubs.rsc.org/en/content/articlelanding/2021/cs/d0cs01459a | issn = 1460-4744 | doi = 10.1039/D0CS01459A | pmid = 34128513}}{{Citace periodika | autor1 = Markéta Navrátilová | autor2 = Karel Sporka | titul = Synthesis of adamantane on commercially available zeolitic catalysts | periodikum = Applied Catalysis A: General | datum vydání = 2000-09-18 | strany = 127–132 | url = https://www.sciencedirect.com/science/article/pii/S0926860X00004774 | issn = 0926-860X | doi = 10.1016/S0926-860X(00)00477-4}}{{Citace periodika | autor1 = Eva María Gallego | autor2 = M. Teresa Portilla | autor3 = Cecilia Paris | autor4 = Alejandro León-Escamilla | autor5 = Mercedes Boronat | autor6 = Manuel Moliner | autor7 = Avelino Corma | titul = "Ab initio" synthesis of zeolites for preestablished catalytic reactions | periodikum = [[Science]] | datum vydání = 2017-03-10 | strany = 1051–1054 | url = https://www.science.org/doi/10.1126/science.aal0121 | issn = 0036-8075 | doi = 10.1126/science.aal0121 | pmid = 28280200 | bibcode = 2017Sci...355.1051G}} přičemž je hlavním produktem ''exo''-izomer.{{Citace periodika | autor1 = Q. I. Lili | autor2 = J. I. Min | autor3 = Wang Xinkui | autor4 = H. E. Min | autor5 = C. A. I. Tianxi | titul = AlCl3/MCM-41 as a Catalyst for Isomerization of ''Endo''-tricyclodecane | periodikum = Chinese Journal of Catalysis | datum vydání = 2010-04-25 | strany = 383 | url = https://www.cjcatal.com/EN/ | issn = 0253-9837}}{{Citace periodika | autor1 = J. K. A. Clarke | autor2 = J. J. Rooney | titul = Stereochemical Approaches to Mechanisms of Hydrocarbon Reactions on Metal Catalysts | periodikum = Advances in Catalysis | datum vydání = 1976 | vydavatel = [[Academic Press]] | strany = 125-183 | url = https://www.sciencedirect.com/science/article/pii/S0360056408603144 | isbn = 9780120078257 | doi = 10.1016/s0360-0564(08)60314-4}} [36] => [37] => == Reference == [38] => {{Překlad | jazyk = en | článek = Tricyclodecane | revize = 1189360186}} [39] => [40] => == Externí odkazy == [41] => * {{Commonscat}} [42] => {{Portály|Chemie}} [43] => [44] => [[Kategorie:Cykloalkany]] [45] => [[Kategorie:Tricyklické sloučeniny]] [46] => [[Kategorie:Letectví]] [] => )
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Tricyklodekan

Tricyklodekan (zkráceně TCD) je tricyklický uhlovodík se vzorcem C10H16. Vytváří dva stereoizomery, endo a exo.

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,'tricyklická molekula','uhlovodíky','stereoizomerie','endo-exo izomerie','reaktivní motor','hustota energie','teplota tání','chlorid hlinitý','oxid křemičitý','zeolit','Kategorie:Cykloalkany','Kategorie:Tricyklické sloučeniny'